Lanthanide absorption spectra1/18/2024 1) In absorption the actinide bands are broader, as they are more greatly. The photophysical properties of Sm and Eu complexes are superior in non-coordinating solvents than those observed in the coordinating solvents. spectra for a given actinide according to the identity of the ligand. These changes suggest solvents influence in changing the symmetry of the field around the Ho and Er ions. In the 4f ̶ 4f absorption spectra, the solvents' effect is reflected on the band shape and oscillator strength of the hypersensitive transitions of ternary Ho (5 G 6 ← 5 I 8) and Er (2 H 11/2 ← 4 I 15/2 and 4 G 11/2 ← 4 I 15/2) complexes. (III) As with transition metals, coordination number six is very common in lanthanide complexes. Luminescence occurs from a lanthanide energy level if. 1 Most importantly, this gives rise to a rich energy-level structure in the near infrared (NIR), visible (VIS), and ultraviolet (UV. The lanthanides are long known as the lighting elements. The lanthanide 4f orbitals are buried beneath the 6s, 5p, and 5d orbitals hence, spectra arising from ff transitions are narrow and insensitive to their environment, unlike transition metal (3d) spectra. Naturally, there are no analogous features for gas phase spectra. The NMR spectra of the complexes show that the complexes are stable in both coordinating and non-coordinating solvents. (II) Electronic spectra of lanthanides show very broad bands. Just as for solid state spectra, broad bands due to the transfer of charge between the metal ion and ligands are present in the spectra of lanthanide ions in solution. The shape analyses reveal that the geometry of these eight-coordinated complexes is very close to triangular dodecahedron with D 2d symmetry. The optimized structures reflect the effect of lanthanide contraction as the average bond distances decreases on going from Ho to Er. The ground state molecular structure of the ternary complexes, (Ln = Ho and Er) and their hydrated parent molecules, were determined using semi-empirical Sparkle/RM1 method. This paper presents the paramagnetic NMR, 4f-4f absorption and photoluminescence properties of the complexes of Sm, Eu, Ho and Er with hexafluoroacetylacetone (hfaa) and 1,10-phenanthroline (phen) in various coordinating and non-coordinating solvents.
0 Comments
Rupaul drag race all stars 6 finale1/18/2024 ![]() As it turns out, Khaleesi Laquifa Wadley may have forseen her fate. Martin, because the third turn of All Stars had more dramatic twists and turns than Shangela's favorite HBO epic-turned-perpetual metaphor. After a jaw-dropping performance, Laganja Estranja is announced the winner and reveals that the group has chosen to eliminate Silky Nutmeg Ganache from the competition.Move over, George R.R. It is revealed that Season 6's Laganja Estranja is this week's Lip Sync Assassin. Team 1 receives all negative critiques, with all four of the queens being the bottom four queens. Bonet being the Top All Star of the week. Team 2 is considered the winning team, with Trinity K. On the runway, the queens must redeem a look that they wore in their previous season. Team 3 consists of Eureka!, Kylie Sonique Love and Scarlet Envy. Team 2 consists of Pandora Boxx, Ra'Jah O'Hara, Trinity K. Davenport, Ginger Minj, Jan and Silky Nutmeg Ganache.
![]() Whether you’re looking for a cool breeze to drift through your home or you want an unobstructed view of your backyard, we have a retractable screen door to fit your needs. Open your home to the great outdoors with a retractable screen door. Retractable screens discreetly retract and disappear when not in use, giving you a clean, and unobstructed view. When you invest in your home with an SPF retractable screen or motorized awning, you can guarantee that we stand behind our products. Our retractable door screens are the perfect addition for french doors, single doors, porches, garage doors and all types of openings. Garage Door Bug Screens Interior Window Shades Balcony Shades Recessed Retractable Screens. Zillow has 42 photos of this 1,150,000 3 beds, 2 baths, 2,394 Square Feet single family home located at 6012 Cat Claw Ln, Bradenton, FL 34210 built in 2023. Whether looking for a way to improve your view or save on energy costs, motorized screens for the patio are a great option. ClearView’s patented “Safe-Glide” Speed Reducer™ insures our doors will retract fully without danger of trapped fingers or a “slamming” return. Our standard features include: Vast range of customizable sizes: From 10’ to 40’ widths and 3 different projection options (8’, 10’ and 12’) Integrated cassette housing. The color-matched frames, along with a variety of threshold types will compliment the doorway and provide years of trouble-free and elegant service. SunPro offers the best value in the awning industry with the most premium features included at no additional cost. All doors can be modified for either left or right side entry. Inswinging or outswinging single doorways, double French doorways, or sliding patio doorways can easily be fitted to provide the perfect contemporary look you are sure to enjoy. Our custom retractable screens will fit almost any household doorway or window opening. has been serving Northeast Florida since 1996, spanning services from Fernandina Beach to Palm Coast and from Jacksonville Beach to Lake City. ![]() Screen your garage or patio area for a bug-free and UV-protected space. If you’re ready to start enjoying the benefits of retractable screens on your Bradenton, FL, property, contact RollShield today. Contact us today to get started or to speak with a member of our team about our industry-leading motorized screens.Let The Fresh Air in and Keep The Bugs Out! Motorized Screens Extend your living space with a large opening motorized screen. Whether you want garage door screens, or a series of screens to enclose your patio space, you can count on the professionals at RollShield to install those screens with precision and care. Interested in having a motorized garage door screen installed at your home in the Sarasota, FL, area? DGD Garage Doors is ready to get the job done. Customizability – We offer these screens in a range of sizes and colors, so we can help you find the perfect options for your home.Ease of operation – You’ll be able to control your motorized screen with a remote, making it simple to operate. Screenmobile of Sarasota, FL is the local area’s best choice for installing or repairing all your window, door and enclosure screens.Enhanced privacy – These garage door screens obscure the view into your garage, providing additional privacy for you and your family.Energy efficiency – Our garage door screens can block UV rays from entering your garage, providing invaluable protection from the sun and making your garage more comfortable.Our motorized garage door screens deliver a range of benefits for homeowners. We have unparalleled experience installing and servicing garage doors throughout Sarasota County, so you can trust that we have the knowledge to get the job done right. ![]() ![]() We are proud to offer motorized garage door screens for homeowners who want to turn their garages into a bug-free zone. Do you wish you could spend time in your Sarasota, Florida, home’s garage without having to deal with annoying mosquitoes and other pests? If so, DGD Garage Doors has the solution you’ve been looking for. Feedme rss reader app ios1/18/2024 Despite my enthusiasm, zero percent of the friends I recommended it to declined to adopt it due to the complexity of the UI. I’ve been an avid and mostly happy NewsBlur user for over a decade. I am excited for future improvements because I know they will be done right. But this reader has the RIGHT features to ensure an excellent reading experience. There are other readers with more features. He takes feedback and he actually implements the feedback that aligns with the app philosophy. John is not only an amazing developer but also you can tell he genuinely cares about Unread and his user bases experiences. ![]() The developer is RESPONSIVE!!! This is so critical in any app I review. Unread is not the RSS reader for Power users or somebody that has hundreds of feeds that they are trying to organize and plow through content (Although I have 160 feeds and Unread still does this for me masterfully). It is designed for you to lay back on your couch and just enjoy reading high quality content from high quality websites and blogs. It’s a minimalist interface (Which I love). Unread is what I would call “Low and slow”. The way it handles formatting of text and content is simply amazing. To put it bluntly Unread provides the best reading experience of any RSS reader out there period. It will be number one of those three depending on your reading tastes. You can manage and cancel your subscriptions by going to your account settings on the App Store after purchase.Īs someone who currently owns or has owned every RSS reader in the App Store I will tell you that Unread ranks as one of the top three. Your account will be charged for renewal within 24 hours prior to the end of the current period. Article actions for sending articles directly to supported bookmarking and read later services, and for sharing via email or iMessage.Ī subscription automatically renews unless it is canceled at least 24 hours before the end of the current period.Additional functionality is available with a $19.99 (USD)/year auto-renewing subscription: Use the VoiceOver escape gesture, a two-finger “Z”, to back out of the current screen.There is an action to mark the article read or unread, an action to share the article, and many others. After selecting an article, invoke the accessibility rotor and then select “Actions”. When on an article list, there are actions available for each article in the list.From any screen you can perform a magic tap, a two-finger double tap, to open a menu of options available for that screen.Every screen and every feature is available to users with vision impairments: It’s like reader mode all the time, and the assortment of color themes is nicely curated.” “Unread is focused on eliminating chrome - it is a pure reading app. “Unread carries a strong history as one of the top RSS clients on iOS, and version 2 ensures that will remain true for a long while yet.” I have a lot of muscle memory there, and I enjoy the design of it quite a bit.” … If you ever use the Clear app for your to-dos or shopping lists where it’s very opinionated, very limited, and very gesture-based, it’s kind of like that for RSS readers. ![]() “On the iPhone I use an app called Unread. READ-LATER SERVICES: Unread provides native support for saving articles to Instapaper, Pinboard, Pocket, Raindrop.io, Readwise, and Safari Reading List. Unread is also optimized for the trackpad and mouse. HARDWARE KEYBOARD SUPPORT: Unread’s keyboard navigation capabilities and keyboard shortcuts make it a joy to use on an iPad with a hardware keyboard. WIDGETS: Unread’s widgets display your most recent articles or unread article counts.ĬACHING: Unread caches webpage text and images for instant loading and offline access. Choose one theme for light mode and another for dark mode. (Subscription required.)ĬOLOR THEMES: Unread provides a variety of different color themes. SAVE TO UNREAD: This share sheet extension creates an article in Unread with the contents of the webpage you are visiting from Safari or any other web browser. SUBSCRIBE TO UNREAD: This share sheet extension lets you subscribe to a website’s feeds while visiting that website from Safari or any other web browser. You can easily switch between feed text and webpage text for any article, or make webpage text the default for individual feeds. OTHER SYNCING OPTIONS: In addition to Unread Cloud, Unread can sync with your Feedbin, Feedly, Fever, Inoreader, or NewsBlur account.ĪUTOMATIC WEBPAGE TEXT: For feeds that contain only article summaries, Unread will display the full article text from the webpage. Create or log in to an Unread Cloud account via Sign in with Apple. UNREAD CLOUD: Unread Cloud is a feed retrieval and syncing system for Unread. ![]() Rediscover the joy of reading your favorite writers with Unread, an RSS reader with beautiful typography, comfortable gesture-based navigation, and a variety of color themes. Audio editor for mac1/18/2024 ![]() Maximum number of rendered audio channelsġ0 (including 7.1.2 Atmos, 7.1 and 5. Yes, alt + mousewheel or arrow up / down sets number of harmonics ![]() Retouch tool (attenuates noise in time-frequency selections) Switch between waveform and spectrogram view in clip editorĪrea (time range, frequency range or combined), brush, freehand and magic wand Hour:Min:Sec:MS, SMPTE (23.98, 24, 25, 29.97 drop frame, 29.97 non-drop frame, 30 fps), Sample index, Bar:beat:tickĪcoustica ARA2 plug-in (clip editor functionality in host applications with ARA2 support) While you are recording, place markers with a single key to remember places you will have to edit afterwards. That is how easy it is to start recording a podcast, a song or a concert. TwistedWave is the ideal tool for: Recording. The tools are powerful and best suited to those with editing experience. TwistedWave, an audio editor for Mac Easy to use, fast, powerful. This editor supports mastering audio, converting files, and batch processing multiple files. You can use it to combine and edit tracks. 4.5 (422) Audacity is an easy-to-use, open-source multi-track audio editor that is used to record and edit audio. Standard cut, copy, paste and mix editingĬleaning Wizard that simplifies LP or tape to CD transfers Twisted Wave is an online audio editor for Mac devices. Ultra fast non-destructive editing engine Audacium is an easy-to-use, multi-track audio editor and recorder for Windows, Mac OS X, GNU/Linux and other operating systems. Timer and input level triggered recording Supported driver models for audio recording and playback (Mac) Supported driver models for audio recording and playback (Windows)ĪSIO, Windows Audio (exclusive and non-exclusive), DirectSound Voice-over artists will enjoy the DeClick:Dialogue and DePlosive:Dialogue tools that help reducing pesky mouth clicks, lip smacks and plosives. The new DeBird reduces bird noise effectively and automatically. As beautiful as bird songs may be, they can be a major disturbance when recording in the field. DeBuzz:Dialogue targets buzz and hum noises such as neon light buzz, AC power hum, RF transmission interference. DeWind:Dialogue reduces wind noise whereas DeRustle:Dialogue reduces clothing rustle and microphone bump noise from lavalier recordings. These plug-ins are available exclusively with Acoustica Premium Edition. Learn more > Express Burn Burn Video and Data DVDs or Blu-ray Discs as well as audio CDs on Windows or Mac. With these video sound editors, you can edit original audio tracks of video clips without affecting relevant videos. This part lists the 3 best free video sound editors for Windows and Mac. In addition to Extract:Dialogue that comes bundled with the Premium Edition, we have trained deep learning models to specifically target common issues in dialogue post-production. Switch Audio Converter Convert audio files from many different file formats into mp3, wav or wma. Best Video Sound Editors for Windows and Mac. You can also import a complete mix into a multitrack session and let Acoustica create separate tracks for each stem automatically. Remix can split a complete mix in up to five stems, and you can adjust the stem levels independently in real-time. Cutting Edge Tools based on Deep Learningīoth the Standard and Premium Editions include the Remix tool based on deep learning. Github pages themes1/17/2024 ![]() The first step in installing a theme is to not install the theme :D, to begin, make a backup of your content (Posts, Pages, text you have written already if you have any) to somewhere safe. This is not a bad thing, it is just that there are sooo many ways to style and configure Jekyll functions. Now here is the rub, most themes need to effectively “take over” your GitHub pages repo in order to function, it is just the nature of how themes work with Jekyll. There may be a bit of trial and error involved when selecting a theme that does not advertise being GitHub pages compatible. The main thing to be aware of when browsing themes is that not all are 100% supported to run on GitHub pages. There are a few places from which to get themes for your GitHub pages site, namely: Site Easier of the theme already does what you want. It is still possible to extend the site beyond the theme yourself, but it takes a lot more care and knowledge to implement. ![]()
Harley davidson bike chopper1/17/2024 ![]() LiveWire has proved itself to deliver the acceleration comparing to any of the Harley Davidson bikes but with more sustainability. Harley Davidson electric bike hasn’t performed any lesser than any of its gas-powered equivalent. Harley Davidson is known for delivering top quality and outstanding performance that outstands others along with its design. Harley electric bikes are on their way but the recently released bike LiveWire is the new generation chopper bike with an Electric motor. Some of the coolest electric bike chopper style that have been released are: ![]() Please click: 60V 2000W Fat Tire Electric Bike Mountain Bicycle Other electric bike chopper style and street styles bikes are coming into the market which is going to change the way we ride bikes. It was a game-changer in the bike industry that such a big brand is changing to EV bikes and it became a hallmark again. But with Harley Davidson electric bike released in 2019 was named LiveWire. With early doubts that electric bikes would be too quiet, too weak, and they won’t take you very far. As the world dynamics are changing EV bikes are getting better year every year in terms of speed, safety, weight, and becoming more intelligent. Once again when the world is changing and shifting towards a new substitute for fuel “electricity”, Harley electric bikes are there to change the tradition of bikes once again.Įlectric bikes not only ensure the performance you expect from a Petroleum fueled custom or performance bike but make it more sustainable. Harley Davidson Sportster motor, also known as “unit motor” due to its simpler and compact design became everyone’s first choice in a chopper. Harley Davidson became famous its marketed heavyweight, cruiser bikes offering engine displacements greater than 700cc. Harley Davidson is known for its rich history and its customization style that gave a new way to the chopper motorcycles style and became a hallmark. In the early 1960s, there was a majority number of people were customizing motorcycles mostly American Manufacturer bikes “Harley Davidson” and a certain style had begun to take hold. The “sissy bar” was the signature handle on many of the choppers. ![]() They were built chopping (modifying) a custom motorcycle or they were built from scratch which made them a symbol of respect in the motorcycle community. They were recognized for their radically modified steering wheels and lengthened forks which gave them a long stretched-out appearance which became everyone’s favorite instantly. Chopper Style Electric Bike are a type of custom motorcycle that emerged in California late 1950’s and instantly became a hallmark. Free instals Mimestream1/17/2024 ![]() If your budget is tight this year, you don't have to pay, but you won't get the next update however, your current version still works and you can keep doing your job using that last version of the software. You pay a subscription for as long as you want regular updates. They have what I think is a fair licensing model that is a compromise that satisfies their need for stable income and my need for control of my budget and upgrade schedule. I've found one company that I've been willing to pay a subscription to for tools. Not exactly exciting content that we're all on the edge of our seat anticipating the next email. In the case of an email app, the content is, ugh, email. Though I doubt we'll see rapid improvements and innovations of the apps that deliver that content, the bulk of the subscription we pay goes to the content creators (at least I hope it does). Streaming services are a perfect example. ![]() And, where subscriptions fit best are when new content is being created for them. There are of course tools that are much more sophisticated, so this isn't a perfect analogy to hardware innovations. Sure, we've seen better balanced hammers created, which are more ergonomic, and production efficiencies, but ultimately it's still a hammer to hammer things. To compare to a hammer, what more can you do to it to improve it. And of course with simple tools like email clients, you quickly plateau on what the tool should actually do. Subscriptions stabilize the income between cycles. That said, I can see it from the business owners' perspective as well. And developers and business owners alike were highly motivated to innovate, and it pushed an iterative development cycle that included those innovations. The longer they use the product, the more stuck they become.Ĭlick to expand.Perpetual license. ![]() And if the business owners are really clever, as they often are, they design the product so that they trap their customers. They give all of that control to the company. For consumers, they lose complete control of their upgrade schedule and budget.Ultimately the founders and especially the company that they sell to will want to reduce cost of maintenance to zero, maximize profits again, while also steadily easing their customer base to higher and higher prices. To use a simple analogy to hardware tools again, consumers are paying forever for a fresh coat of paint on their hammer every year or so (whether they needed or wanted a new color). And, the bad part for consumers, is the innovation slows to a crawl, updates, and features trickle out if at all, but often they are just superficial revisions made to give the illusion of modernization.This sucks because you pour your heart, soul, life into building something awesome, and then you're cut out before any big payday happens. Oust that team of developers to maximize profit margins and hand off maintenance to a smaller and much lower cost team.Nothing wrong with that, but that step is the death knell for the original developers. All great software development processes. They push them hard to stabilize the product, setup various processes to automate and simplify maintenance.Founders, owners, or investors hire the best developers they can find, and that team builds a great product.It's a common strategy that I've experienced on the wrong end: So, we consumers get better products.įrom my perspective, subscription based tools create the wrong incentives. Somehow this has worked for decades upon decades and still does. How does any hardware tool manufacturer stay in business? They innovate. Click to expand.I ask the same questions. Johnny Dixon was someone I heard a lot about all offseason, and it’s carried into the season as the starter opposite King. Kalen King has stepped into the role of a shutdown corner. It’s an elite group, even after losing CB Joey Porter Jr. ![]() Snyder: So much has been talked said and written about Allar and the offense, but you’re right about the defense. What makes this year’s version different from those in the past? Speaking of which, from what I’ve seen, Penn State might have the best defense in the country. I think this defense will become one of the nation’s 10 best by season’s end, but they still have work to do. He’s a high-level cover corner and a special player if he touches the ball. No Big Ten team has more first-team all-conference DBs than Iowa since 2009, and DeJean is the best of the bunch. They’re so disciplined that when quarterbacks try to do too much, that’s when the interceptions happen. What Iowa does best on the back end is play zone with eyes always on the quarterback. But they are deep up front and have talent, so that will come in time. Their first three opponents have opted for quick passing games to negate the pass rush, and that has prevented them from getting sacks. Losing first-rounders like Jack Campbell and Lukas Van Ness along with NFL players Riley Moss and Kaevon Merriweather has the Hawkeyes working through a few issues. This is a quality defense right now, but it’s still a little off from last year’s elite-level unit. Three were on passing plays of 50-plus yards, and three were in the final two minutes of action in garbage time. How has he looked overall and what happened last week at Illinois?ĭochterman: Organically grown, Penn State-Iowa has become the Big Ten's best rivalry that's not a rivalryĭochterman: The Hawkeyes have won eight of their last nine games and allowed 10 total touchdowns. It’s certainly no thing of beauty, but it’s the outcome that matters, right? On that note, I’ve been fascinated to watch Drew Allar’s growth from elite prospect to starter. But I’ve seen more pedestrian Iowa offenses work through these conditions, provided they take care of the ball. The Hawkeyes finally have an ascending offensive line, but I know what they face this week, so at best it may be a stalemate. Injuries to Kaleb Johnson and Jaziun Patterson will limit the running game, although Iowa has one more upper-level runner in Leshon Williams. ![]() Not to be hyperbolic, but junior Luke Lachey was playing as well as any Iowa tight end I’ve seen and is definitely in the same grouping as T.J. Iowa is capable of playing that Rocky Balboa to Penn State’s Apollo Creed type of game, but the injuries on offense make it much more difficult to pull it off. Can Iowa do that, given the current health of its roster?ĭochterman: Great question, Audrey. Penn State expects this to be one of those grind-it-out kind of games. But James Franklin said Tuesday that we all know Iowa and what kind of game this could be. The big question here is starting wide receiver Harrison Wallace III, who warmed up but didn’t play against Illinois. Penn State is mostly healthy at this point. I’m not sure they’ll be that cheeky, but I would do it.īecause injuries - perceived or otherwise - are now on our minds, I wanted to ask you about what Iowa does without its top running backs. ![]() Penn State has a real opportunity Saturday night during to lean into this and play Taylor Swift’s “Bad Blood” during warmups. Snyder: It’s the White Out game with lots of bad blood mixed in thanks to injury-gate. Which ones were the most memorable?ĭochterman: So, Audrey, here we are two years after “Scuba” and “Turtle.” It almost seems like this matchup deserves a “gate” moniker of some sorts. Demilich mtg1/17/2024 Cyclone SummonerĬyclone Summoner works as a kind of overloaded Cyclonic Rift in the line of an Aegar, the Freezing Flame giant-wizard tribal while also giving you a pretty threatening 7/7 giant. Green is the color with the fewest wizards. Second on the list is black followed by white and red. Almost half of all wizard cards are mono-blue, and a significant bunch are blue with another color. That being said, there are more wizards in blue than there are in every other color combined. You'll find wizards in every color in Magic. The only consistent part of wizards is the fact that they share a creature type. ![]() They go from 0/1 creatures like Apprentice Wizard to 8/8 giants (quite literally) like Surtland Elementalist. Wizards can also vary in power and toughness. ![]() But there are still a lot of wizards that simply have a variety of abilities. Other wizards have a prevalent focus on drawing cards. A lot of them have effects that help cast spells, benefit from you casting them, or interact with those spells in some way. Wizards are spellcasters and characters who’ve spent their lives studying and becoming versed in magic. Please remember it can take some time for your bank or credit card company to process and post the refund too.Thassa's Oracle | Illustration by Jesper Ejsing If approved, you’ll be automatically refunded on your original payment method within 10 business days. We will notify you once we’ve received and inspected your return, and let you know if the refund was approved or not. You’ll also need the receipt or proof of purchase. As above, your item must be in the same condition that you received it, unworn or unused, with tags, and in its original packaging. Notwithstanding the above, if the merchandise is being shipped into the European Union, you have the right to cancel or return your order within 14 days, for any reason and without a justification. The fastest way to ensure you get what you want is to return the item you have, and once the return is accepted, make a separate purchase for the new item. Unfortunately, we cannot accept returns on sale items or gift cards. Please get in touch if you have questions or concerns about your specific item. ![]() We also do not accept returns for hazardous materials, flammable liquids, or gases. ) and custom products (such as special orders or personalized items). Please inspect your order upon reception and contact us immediately if the item is defective, damaged or if you receive the wrong item, so that we can evaluate the issue and make it right.Ĭertain types of items cannot be returned, like TCG (such as booster packs, boxes, gift bundles ect. You can always contact us for any return question at and issues Items sent back to us without first requesting a return will not be accepted. If your return is accepted, we’ll send instructions on how and where to send your package. To start a return, you can contact us at Please note that returns will need to be sent to the following address: To be eligible for a return, your item must be in the same condition that you received it, unworn or unused, with tags, and in its original packaging. We have a 30-day return policy, which means you have 30 days after receiving your item to request a return. AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |